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学科主题: 金属有机化学
题名: Preparation of novel axially chiral NHC-Pd(II) complexes and their application in oxidative kinetic resolution of secondary alcohols
其他题名: 具有轴手性的氮杂卡宾金属钯络和物的合成及其在二级醇氧化动力学拆分中的应用
作者: Liu SJ(刘思佳) ; Liu LJ(刘连军) ; Shi M(施敏)
刊名: Appl. Organomet. Chem.
发表日期: 2009
卷: 23, 期:5, 页:183-190
收录类别: SCI
部门归属: 华东理工大学; 上海有机所
英文摘要: Novel axially chiral N-heterocyclic carbene (NHC) Pd(II) complexes were prepared from optically active 1,1'-binaphthalenyl-2,2'-diamine (BINAM) and H-8-BINAM and their crystal structures were unambiguously determined by X-ray diffraction. These chiral N-heterocyclic carbene (NHC) Pd(II) complexes were applied in the oxidative kinetic resolution of secondary alcohols using molecular oxygen as a terminal oxidant or under aerobic conditions, affording the corresponding sec-alcohols in good yields with moderate to good enantioselectivities. Copyright (C) 2009 John Wiley & Sons, Ltd.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000265556400003
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/10288
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Liu SJ,Liu LJ,Shi M. Preparation of novel axially chiral NHC-Pd(II) complexes and their application in oxidative kinetic resolution of secondary alcohols[J]. Appl. Organomet. Chem.,2009,23(5):183-190.
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