中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 金属有机化学国家重点实验室  > 期刊论文
学科主题: 金属有机化学
题名: Lithium Diisopropylamide-Mediated Carbolithiation Reactions of Vinylidenecyclopropanes and Further Transformations of the Adducts
其他题名: LDA促进的亚乙烯基环丙烷碳锂化反应和产物的进一步转化
作者: Lu JM(陆建梅) ; Shi M(施敏)
通讯作者: 施敏
刊名: Chem.-Eur. J.
发表日期: 2009
卷: 15, 期:24, 页:6065-6073
收录类别: SCI
部门归属: 上海有机所; 温州大学
英文摘要: Highly stereo- and regioselective carbolithiation reactions of vinylidenecyclopropanes 1 were realized by treatment with lithium diisopropylamide (LDA) in THF and by quenching with various electrophiles such as aryl or aliphatic aldehydes, ketones, enones or propargyl bromide. Transformation of these adducts such as vinylcyclopropenes and allenols was also performed in the presence of Lewis acid or Bronsted acid to provide the fused and conjugated aromatic products in good to high yields under mild conditions.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000267278900025
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/10278
Appears in Collections:金属有机化学国家重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2009244.pdf(333KB)----开放获取--View Download

Recommended Citation:
Lu JM,Shi M. Lithium Diisopropylamide-Mediated Carbolithiation Reactions of Vinylidenecyclopropanes and Further Transformations of the Adducts[J]. Chem.-Eur. J.,2009,15(24):6065-6073.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[Lu JM(陆建梅)]'s Articles
[Shi M(施敏)]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[Lu JM(陆建梅)]‘s Articles
[Shi M(施敏)]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2009244.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace