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学科主题: 金属有机化学
题名: Synthesis of Chiral Bis(N-heterocyclic carbene) Palladium and Rhodium Complexes with 1,1 '-Biphenyl Scaffold and Their Application in Asymmetric Catalysis
其他题名: 具有联苯骨架的手性氮杂环卡宾配体的合成及其在不对称催化反应中的应用
作者: Liu LJ(刘连军) ; Wang FJ(王飞军) ; Shi M(施敏)
刊名: Organometallics
发表日期: 2009
卷: 28, 期:15, 页:4416-4420
收录类别: SCI
部门归属: 华东理工大学; 上海有机所
英文摘要: Axially chiral bis(NFIC) Pd(II) and Rh(III) complexes with 1,1'-biphenyl scaffold have been successfully synthesized from the corresponding chiral 6,6'-dimethoxybiphenyl-2-2'-diamine. These interesting NFIC-metal complexes have been characterized by X-ray crystal structure diffraction. When applied in the oxidative kinetic resolution of sec-alcohols and hydrosilylation of ketones, these catalysts showed good catalytic activities with moderate to high enantioselectivities.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000268455900027
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/10270
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Liu LJ,Wang FJ,Shi M. Synthesis of Chiral Bis(N-heterocyclic carbene) Palladium and Rhodium Complexes with 1,1 '-Biphenyl Scaffold and Their Application in Asymmetric Catalysis[J]. Organometallics,2009,28(15):4416-4420.
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