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Synthesis of Chiral Bis(N-heterocyclic carbene) Palladium and Rhodium Complexes with 1,1 '-Biphenyl Scaffold and Their Application in Asymmetric Catalysis
其他题名具有联苯骨架的手性氮杂环卡宾配体的合成及其在不对称催化反应中的应用
Liu LJ(刘连军); Wang FJ(王飞军); Shi M(施敏)
2009
发表期刊Organometallics
ISSN0276-7333
卷号28期号:15页码:4416-4420
摘要Axially chiral bis(NFIC) Pd(II) and Rh(III) complexes with 1,1'-biphenyl scaffold have been successfully synthesized from the corresponding chiral 6,6'-dimethoxybiphenyl-2-2'-diamine. These interesting NFIC-metal complexes have been characterized by X-ray crystal structure diffraction. When applied in the oxidative kinetic resolution of sec-alcohols and hydrosilylation of ketones, these catalysts showed good catalytic activities with moderate to high enantioselectivities.
学科领域金属有机化学
部门归属华东理工大学; 上海有机所
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收录类别SCI
语种英语
WOS记录号WOS:000268455900027
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文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/10270
专题金属有机化学国家重点实验室
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GB/T 7714
Liu LJ,Wang FJ,Shi M. Synthesis of Chiral Bis(N-heterocyclic carbene) Palladium and Rhodium Complexes with 1,1 '-Biphenyl Scaffold and Their Application in Asymmetric Catalysis[J]. Organometallics,2009,28(15):4416-4420.
APA 刘连军,王飞军,&施敏.(2009).Synthesis of Chiral Bis(N-heterocyclic carbene) Palladium and Rhodium Complexes with 1,1 '-Biphenyl Scaffold and Their Application in Asymmetric Catalysis.Organometallics,28(15),4416-4420.
MLA 刘连军,et al."Synthesis of Chiral Bis(N-heterocyclic carbene) Palladium and Rhodium Complexes with 1,1 '-Biphenyl Scaffold and Their Application in Asymmetric Catalysis".Organometallics 28.15(2009):4416-4420.
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