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学科主题: 金属有机化学
题名: Nd(OTf)(3)-Catalyzed Cascade Reactions of Vinylidenecyclopropanes with Enynol: A New Method for the Construction of the 5-7-6 Tricyclic Framework and Its Scope and Limitations
其他题名: Nd(OTf)3催化的亚乙烯基环丙烷化合物和烯炔的串联反应-构建5-7-6双环体系
作者: Yao LF(姚梁峰) ; Shi M(施敏)
刊名: Eur. J. Org. Chem.
发表日期: 2009
期: 24, 页:4036-4040
收录类别: SCI
部门归属: 华东理工大学; 上海有机所
英文摘要: We report in this paper a Lewis acid [Nd(OTf)(3)]-catalyzed protocol to construct compounds containing a 5-7-6 tricyclic framework in good yield from readily accessible starting materials vinylidenecyclopropanes (VDCPs) 1 and enynols 2a-c under mild conditions. Upon examination of the scope and limitations of this reaction, it was found that the corresponding highly functionalized cyclopentane derivatives could be formed in good yields from the reaction VDCPs 1 and enol 2e or dienol 2c under identical conditions. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000269221800003
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/10262
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Yao LF,Shi M. Nd(OTf)(3)-Catalyzed Cascade Reactions of Vinylidenecyclopropanes with Enynol: A New Method for the Construction of the 5-7-6 Tricyclic Framework and Its Scope and Limitations[J]. Eur. J. Org. Chem.,2009(24):4036-4040.
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