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Nd(OTf)(3)-Catalyzed Cascade Reactions of Vinylidenecyclopropanes with Enynol: A New Method for the Construction of the 5-7-6 Tricyclic Framework and Its Scope and Limitations
其他题名Nd(OTf)3催化的亚乙烯基环丙烷化合物和烯炔的串联反应-构建5-7-6双环体系
Yao LF(姚梁峰); Shi M(施敏)
2009
发表期刊Eur. J. Org. Chem.
ISSN1434-193X
期号24页码:4036-4040
摘要We report in this paper a Lewis acid [Nd(OTf)(3)]-catalyzed protocol to construct compounds containing a 5-7-6 tricyclic framework in good yield from readily accessible starting materials vinylidenecyclopropanes (VDCPs) 1 and enynols 2a-c under mild conditions. Upon examination of the scope and limitations of this reaction, it was found that the corresponding highly functionalized cyclopentane derivatives could be formed in good yields from the reaction VDCPs 1 and enol 2e or dienol 2c under identical conditions. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
学科领域金属有机化学
部门归属华东理工大学; 上海有机所
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收录类别SCI
语种英语
WOS记录号WOS:000269221800003
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文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/10262
专题金属有机化学国家重点实验室
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GB/T 7714
Yao LF,Shi M. Nd(OTf)(3)-Catalyzed Cascade Reactions of Vinylidenecyclopropanes with Enynol: A New Method for the Construction of the 5-7-6 Tricyclic Framework and Its Scope and Limitations[J]. Eur. J. Org. Chem.,2009(24):4036-4040.
APA 姚梁峰,&施敏.(2009).Nd(OTf)(3)-Catalyzed Cascade Reactions of Vinylidenecyclopropanes with Enynol: A New Method for the Construction of the 5-7-6 Tricyclic Framework and Its Scope and Limitations.Eur. J. Org. Chem.(24),4036-4040.
MLA 姚梁峰,et al."Nd(OTf)(3)-Catalyzed Cascade Reactions of Vinylidenecyclopropanes with Enynol: A New Method for the Construction of the 5-7-6 Tricyclic Framework and Its Scope and Limitations".Eur. J. Org. Chem. .24(2009):4036-4040.
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