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学科主题: 金属有机化学
题名: N-heterocyclic carbene sulfonamide palladium complexes and their catalytic activities in Suzuki-Miyaura coupling reaction
其他题名: 双氮杂环卡宾-磺酰胺金属钯配合物的合成及其催化的Suzuki-Miyaura偶联反应
作者: Zhang T(张涛) ; Wang WF(王文丰) ; Gu XX(顾星星) ; Shi M(施敏)
通讯作者: 施敏
刊名: Organometallics
发表日期: 2008
卷: 27, 期:4, 页:753-757
收录类别: SCI
部门归属: 华东理工大学; 中科院上海有机所金属有机化学国家重点实验室
英文摘要: Novel N-heterocyclic carbene sulfonamide ligands derived from binaphthyl-2,2'-diamine (BINAM) and their tridentate NHC-Pd(II) complexes as well as their corresponding NHC-Pd(II) complexes bearing weakly coordinating acetate counterions have been successfully synthesized in good yields. These NHC-palladium(II) complexes have been characterized by X-ray crystal structure diffraction. Moreover, we found that these NHC-Pd(II) complexes bearing weakly coordinating acetate counterions are quite effective in Suzuki-Miyaura coupling reaction to give the corresponding products in good to excellent yields in most cases at room temperature in 2-propanol in the presence of sodium tert-butoxide.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000253268000037
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/10218
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Zhang T,Wang WF,Gu XX,et al. N-heterocyclic carbene sulfonamide palladium complexes and their catalytic activities in Suzuki-Miyaura coupling reaction[J]. Organometallics,2008,27(4):753-757.
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