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学科主题: 元素有机化学
题名: Chiral phosphine-catalyzed enantioselective construction of gamma-butenolides through substitution of Morita-Baylis-Hillman acetates with 2-trimethylsilyloxy furan
其他题名: 手性膦化合物催化的通过Morita-Baylis-Hillman反应产物和呋喃硅醚的反应进行??-丁内酯的不对称合成
作者: Jiang YQ(姜迎庆) ; Shi YL(时永灵) ; Shi M(施敏)
通讯作者: 施敏
刊名: J. Am. Chem. Soc.
发表日期: 2008
卷: 130, 期:23, 页:7202-6937
收录类别: SCI
部门归属: 中科院上海有机所金属有机化学国家重点实验室
英文摘要: Chiral multifunctional phosphine (R)-N-(2'-diphenylphosphanyl-[1,1']binaphthalenyl-2-yl) methanesulfonamide L2 or (R)-N-(2'-diphenylphosphanyl-[1,1']binaphthalenyl-2-yl) acetamide L3 is an efficient catalyst in the substitutions of MBH acetates 1 with 2-trimethylsilyloxy furan 2 to provide y-butenolides 3 in good to excellent yields and enantiomeric excesses in the presence of water.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000256550600018
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/10196
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Jiang YQ,Shi YL,Shi M. Chiral phosphine-catalyzed enantioselective construction of gamma-butenolides through substitution of Morita-Baylis-Hillman acetates with 2-trimethylsilyloxy furan[J]. J. Am. Chem. Soc.,2008,130(23):7202-6937.
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