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学科主题: 金属有机化学
题名: The use of chiral BINAM NHC-Rh(III) complexes in enantioselective hydrosilylation of 3-oxo-3-arylpropionic acid methyl or ethyl esters
其他题名: 手性氮杂卡宾配体和金属铑配和物在?-酮酸酯的不对称还原中的应用
作者: Xu Q(徐琴) ; Gu XX(顾星星) ; Liu SJ(刘思佳) ; Dou QY(窦清玉) ; Shi M(施敏)
刊名: J. Org. Chem.
发表日期: 2007
卷: 72, 期:6, 页:2240-2242
收录类别: SCI
部门归属: 华东理工; 中科院上海有机所金属有机化学国家重点实验室
英文摘要: Axially chiral BINAM N-heterocyclic carbene (NHC)-Rh-(III) complexes were applied in the enantioselective hydrosilylation of 3-oxo-3-arylpropionic acid methyl or ethyl esters. The reduction products 3-hydroxy-3-arylpropionic acid methyl or ethyl esters could be obtained in good yields with good to excellent enantioselectivities under mild conditions.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000244773600047
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/10110
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Xu Q,Gu XX,Liu SJ,et al. The use of chiral BINAM NHC-Rh(III) complexes in enantioselective hydrosilylation of 3-oxo-3-arylpropionic acid methyl or ethyl esters[J]. J. Org. Chem.,2007,72(6):2240-2242.
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