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FeCl3-catalyzed aminohalogenation of arylmethylenecyclopropanes and arylvinylidenecyclopropanes and corresponding mechanistic studies
Alternative Title三氯化铁催化的亚乙烯基环宾烷和亚甲基环宾烷的胺卤化反应
Li QJ(李清江); Shi M(施敏); Cody Timmons; Li GG(李桂根); Shi M(施敏); Li GG(李桂根)
2006
Source PublicationOrg. Lett.
Volume8Issue:4Pages:625-628
AbstractThe aminochlorination of methylenecyclopropanes (MCPs) 1 and vinylidenecyclopropanes (VCPs) has been explored with use of FeCl3 (20 mol %) as a Lewis acid catalyst in acetonitrile under convenient mild conditions. The stereochemistry has been unambiguously confirmed by X-ray structural analysis. The aziridinium-based mechanism, accounting for both regio- and stereoselectivity, has been carefully studied. A linear free-energy relationship study of this reaction confirms consistency with the Hammet equation.
Subject Area金属有机化学
Department中科院上海有机所金属有机化学国家重点实验室; Tex Tech
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Indexed BySCI
Language英语
WOS IDWOS:000235534800020
Citation statistics
Cited Times:69[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/10056
Collection金属有机化学国家重点实验室
Corresponding AuthorShi M(施敏); Li GG(李桂根)
Recommended Citation
GB/T 7714
Li QJ,Shi M,Cody Timmons,et al. FeCl3-catalyzed aminohalogenation of arylmethylenecyclopropanes and arylvinylidenecyclopropanes and corresponding mechanistic studies[J]. Org. Lett.,2006,8(4):625-628.
APA Li QJ,Shi M,Cody Timmons,Li GG,施敏,&李桂根.(2006).FeCl3-catalyzed aminohalogenation of arylmethylenecyclopropanes and arylvinylidenecyclopropanes and corresponding mechanistic studies.Org. Lett.,8(4),625-628.
MLA Li QJ,et al."FeCl3-catalyzed aminohalogenation of arylmethylenecyclopropanes and arylvinylidenecyclopropanes and corresponding mechanistic studies".Org. Lett. 8.4(2006):625-628.
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