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学科主题: 金属有机化学
题名: FeCl3-catalyzed aminohalogenation of arylmethylenecyclopropanes and arylvinylidenecyclopropanes and corresponding mechanistic studies
其他题名: 三氯化铁催化的亚乙烯基环宾烷和亚甲基环宾烷的胺卤化反应
作者: Li QJ(李清江) ; Shi M(施敏) ; Cody Timmons ; Li GG(李桂根)
通讯作者: 施敏 ; 李桂根
刊名: Org. Lett.
发表日期: 2006
卷: 8, 期:4, 页:625-628
收录类别: SCI
部门归属: 中科院上海有机所金属有机化学国家重点实验室; Tex Tech
英文摘要: The aminochlorination of methylenecyclopropanes (MCPs) 1 and vinylidenecyclopropanes (VCPs) has been explored with use of FeCl3 (20 mol %) as a Lewis acid catalyst in acetonitrile under convenient mild conditions. The stereochemistry has been unambiguously confirmed by X-ray structural analysis. The aziridinium-based mechanism, accounting for both regio- and stereoselectivity, has been carefully studied. A linear free-energy relationship study of this reaction confirms consistency with the Hammet equation.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000235534800020
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/10056
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Li QJ,Shi M,Cody Timmons,et al. FeCl3-catalyzed aminohalogenation of arylmethylenecyclopropanes and arylvinylidenecyclopropanes and corresponding mechanistic studies[J]. Org. Lett.,2006,8(4):625-628.
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