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学科主题: 金属有机化学
题名: A stereoselective synthetic route to 1,6-dioxaspiro[4.4]non-3-en-2-ones from cyclopropyl alkyl ketones and alpha-ketoesters
其他题名: 从环丙基烷基酮和?-Ketoesters的反应制备螺环类化合物的方法
作者: Yang YH(杨永华) ; Shi M(施敏)
通讯作者: 施敏
刊名: Org. Lett.
发表日期: 2006
卷: 8, 期:8, 页:1709-1712
收录类别: SCI
部门归属: 中科院上海有机所金属有机化学国家重点实验室
英文摘要: The SnCl4-mediated reactions of cyclopropyl alkyl ketones with alpha-ketoesters afford a novel method for the synthesis of 1,6-dioxaspiro[4.4]non-3-en-2-ones with high stereoselectivities in moderate to good yields. This process is a sequential reaction involving a nucleophilic ring-opening reaction of the cyclopropane by H2O, an aldol-type reaction, and a cyclic transesterification mediated by Lewis acid.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000236950400050
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/10048
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Yang YH,Shi M. A stereoselective synthetic route to 1,6-dioxaspiro[4.4]non-3-en-2-ones from cyclopropyl alkyl ketones and alpha-ketoesters[J]. Org. Lett.,2006,8(8):1709-1712.
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